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There are also some events that were giving out these cards to the public, according to @Quuador : Thanks for the info

Put Knuckles behind a Walls of Ba Sing Say and alongside an Academy Manufactor and just bide your time to victory

Six Samurai Deck SKU: $10.99 $8.99 $8.99 Unavailable per item Monsters [15] 1 Elder of the Six Samurai 1 Grandmaster of the Six Samurai 3 Kagemusha of the Six Samurai 1 Legendary Six Samurai - Enishi 2 Legendary Six Samurai - Kageki 3 Legendary Six Samurai - Kizan 2 Maxx "C" 1 The Six Samurai - Irou 1 The Six Samurai - Zanji Spells [13] 3 Asceticism of the Six Samurai 1 Gateway of the Six 1 Heavy Storm 1 Monster Reborn 1 Mystical Space Typhoon 1 Reinforcement of the Army 2 Shien's Smoke Signal 3 Six Samurai United Traps [12] 2 Bottomless Trap Hole 2 Compulsory Evacuation Device 2 Dimensional Prison 1 Double-Edged Sword Technique 2 Musakani Magatama 1 Solemn Judgment 2 Solemn Warning Deck Total [40] Extra Deck [15] 1 Adreus, Keeper of Armageddon 1 Ally of Justice Catastor 1 Ally of Justice Decisive Armor 1 Blade Armor Ninja 1 Chimeratech Fortress Dragon 1 Heroic Champion - Excalibur 1 Legendary Six Samurai - Shi En 1 Mist Wurm 1 Naturia Barkion 1 Naturia Beast 1 Number 16: Shock Master 1 Number 39: Utopia 1 Shadow of the Six Samurai - Shien 1 Temtempo the Percussion Djinn 1 Wind-Up Zenmaines 1 Elder of the Six Samurai 1 Grandmaster of the Six Samurai 3 Kagemusha of the Six Samurai 1 Legendary Six Samurai - Enishi 2 Legendary Six Samurai - Kageki 3 Legendary Six Samurai - Kizan 2 Maxx "C" 1 The Six Samurai - Irou 1 The Six Samurai - Zanji Spells [13] 3 Asceticism of the Six Samurai 1 Gateway of the Six 1 Heavy Storm 1 Monster Reborn 1 Mystical Space Typhoon 1 Reinforcement of the Army 2 Shien's Smoke Signal 3 Six Samurai United Traps [12] 2 Bottomless Trap Hole 2 Compulsory Evacuation Device 2 Dimensional Prison 1 Double-Edged Sword Technique 2 Musakani Magatama 1 Solemn Judgment 2 Solemn Warning Deck Total [40] Extra Deck [15] 1 Adreus, Keeper of Armageddon 1 Ally of Justice Catastor 1 Ally of Justice Decisive Armor 1 Blade Armor Ninja 1 Chimeratech Fortress Dragon 1 Heroic Champion - Excalibur 1 Legendary Six Samurai - Shi En 1 Mist Wurm 1 Naturia Barkion 1 Naturia Beast 1 Number 16: Shock Master 1 Number 39: Utopia 1 Shadow of the Six Samurai - Shien 1 Temtempo the Percussion Djinn 1 Wind-Up Zenmaines

That would probably be a higher risk than reward though, since it could be sold for college tuition

Promotional Powerless Piece of Garbage: Most Promo Pokmon tied to events are deliberately undertuned or are reskins of already-existing cards, but are also exclusive to their events and can't be traded